Product ID:AUTOCOAT LV HARDENER HIGH SOLIDS 004445-1007451
MSDS Date:01/01/1995
FSC:8010
NIIN:00N075007
MSDS Number: CCTJW

AKZO NOBEL COATINGS INC

5555 SPALDING DR
NORCROSS, GA 30092
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 404-441-8628

Cage: AKZNB

AKZO NOBEL COATINGS INC

NORCROSS, GA 30092 US

Telephone: 770-662-8464; 770-441-8628

Cage: AKZNB

ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (CERCLA)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 1-5%

OSHA PEL 150 PPM

ACGIH TLV: 150 PPM/200STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ISOCYANIC ACID, HEXAMETHYLENE ESTER, POLYMERS;

CAS: 28182-81-2

RTECS: NQ9170000

Fraction By Weight: 40-70%

OSHA PEL N/K

ACGIH TLV: 0.5 MG/M3 (MFR)

HEXANE, 1,6-DIISOCYANATO-; (HEXAMETHYLENE DIISOCYANATE

CAS: 822-06-0

RTECS: MO1740000

Fraction By Weight: 0.17%

OSHA PEL N/K

ACGIH TLV: 0.005 MG/M3 (MFR)

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ISOCYANIC ACID, METHYLENE

CAS: 4098-71-9

RTECS: NQ9370000

Fraction By Weight: 0.13%

OSHA PEL 0.02 MG/M3 (MFR)

ACGIH TLV: 0.005 PPM

2.1;

CAS: 541-85-5

RTECS: MJ7350000

Fraction By Weight: 5-10%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM

1600;

CAS: 110-43-0

RTECS: MJ5075000

Fraction By Weight: 5-10%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM

10.0;

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 1.0%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/125STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

4300;

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 4.8%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (PROPYLENE

CAS: 108-65-6

RTECS: AI8925000

Fraction By Weight: 1-5%

OSHA PEL N/K

ACGIH TLV: N/K

FROM DHHS (NIOSH) PUBLICATION NO 90-118) .

RTECS: 9999999ZZ

DISORDERS, RED BLOOD CELL & LEUKOCYTE DISORDERS

RTECS: 9999999ZZ

MIXED W/PROPER COMPONENTS & SPRAYED PROD HAS BEEN

RTECS: 9999999ZZ

KIDNEY & BLOOD SYS DMG. OTHER HLTH

RTECS: 9999999ZZ

CONTENTS MAY BE HARMFUL/FATAL. RPTS HAVE ASSOC RPTD

RTECS: 9999999ZZ

SYS DMG. AROMATIC HYDROCARBONS HAVE BEEN SHOWN IN

RTECS: 9999999ZZ

FORMING TISS & MAY IN RARE CASES SENSITIZE HEART

RTECS: 9999999ZZ

SHOWN IN ANIMAL STUDIES TO CAUSE ADVERSE EFTS ON

RTECS: 9999999ZZ

TOX. 4 HR LC50 OF 160 PPM IN MALE & FEMALE RATS HAS

RTECS: 9999999ZZ

ISOCYANATES MAY CAUSE SKIN & RESP SYS SENSIT CAUSING

RTECS: 9999999ZZ

DURING HEATING. REMOVE DECOMP PRODS FORMED DURING

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:NASAL & RESP IRRIT, DIZZ,
WEAK, FATG, NAUS, HDCH, POSS UNCONS, CHEM PNEUM, CNS DEPRESS & EVEN
ASPHY. SKIN:EXTRACTION OF NATURAL OILS W/RSLTING DRY SKIN, IRRIT,
REDNESS & DERM. EYE:IRRIT, R EDNESS, PAIN, BLURRED VISION,
SENSATIONOF SEEING HALOS AROUND LIGHTS. WHEN MIXED W/PROPER
COMPONENTS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:& SPRAYED PROD HAS BEEN KNOWN TO
OCCAS CAUSE PAIN IN SHORT TERM. INGEST:GI IRRIT, NAUS, VOMIT &
DIARR. CHRONIC:ANIMAL STUDIES CLEARLY DEMONSTRATED DOSE-RELATED
ADVERSE EFTS ON CNS, HEMATOPOI ETIC TISS, BLOOD, KIDNEYS & LIVER,
ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE (EGBEA)
EXTRACTED (ING 10)
Medical Cond Aggravated by Exposure:ISOCYANATE SENSITIZATION, SKIN
DISORDERS, EYE DISORDERS.

First Aid:INHALATION:MOVE TO FRESH AIR, GIVE ARTIFICIAL RESPIRATION IF
NECESSARY. SKIN CONTACT:WASH WITH SOAP AND WATER, NOT SOLVENT. EYE
CONTACT:FLUSH WITH WATER FOR AT LEAST 15 MINUTES, CONSULT A
PHYSICIAN. I NGESTION:DRINK ONE OR TWO GLASSES OF WATER TO DILUTE.
DO NOT INDUCE VOMITING. CONSULT A PHYSICIAN OR POISON CONTROL
CENTER IMMEDIATELY. TREAT SYMPTOMATICALLY.

Flash Point:106F,41C
Lower Limits:1.0%
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICALS.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . WATER SHOULD BE USED TO COOL CONTAINERS EXPOSED TO
FIRE.
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD, ISOLATE FROM
HEAT, ELEC EQUIP, SPKS & OPEN FLAMES. CLSD CNTNRS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. APPLICATN TO HOT (SUPDAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID
BREATHING VAPORS, VENTILATE CONFINED AREA. DIKE TO REDUCE EXTENT OF
SPILL. REMOVE WITH INERT ABSORBENT USING NON-SPARKING TOOLS. IF
NECESSARY, REPORT TO APPLICABL E GOVERNMENT AGENCY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE CNTNRS OUT OF SUN & AWAY FROM
HEAT, SPKS, & OPEN FLAMES. CLOSE ALL CNTNRS AFTER EACH USE. CONSULT
NFPA & LOC CODES FOR ADDNL STOR REQS.
Other Precautions:USE APPRVD BONDING & GROUNDING PROCEDURES. OBSERVE
LBL PRECS. KEEP CLOSURES TIGHT & CNTNR UPRIGHT TO PVNT LEAKAGE.
AVOID BRTHG SANDING DUST. DO NOT WELD/FLAME CUT ON EMPTY DRUM. WHEN
SPRAYING PROD USE MAX PERS PROT EQUIP; COVER ALL (SUPDAT)

Respiratory Protection:ADEQ VENT IS REQD. PROD CNTNS ISOCYANATES. USE
NIOSH APPRVD POS PRESS AIR SUPPLY RESP. SEE SFTY EQUIP SUPP FOR
EVAL & REC. IN CASES WHERE NO MONITORING FOR AIRBORNE CONTAMS HAS
BEEN CARRIED OUT, ASSUM E MAX EXPOS & USE PAINT SUIT, (SUPDAT)
Ventilation:PROVIDE SUFFICIENT VENT TO KEEP VAP CONCS BELOW GIVEN TLV
&/OR PEL. FOR BAKING ASHES, EXHST VAPS EMITTED (ING 20)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER .
USE CHEM RESIST APRON, BOOTS/OTHER CLTHG IF NEEDED.
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING OR USING THE
WASHROOM. LAUNDER CLOTHING BEFORE REUSE.
Supplemental Safety and Health
EXPLO HAZS:SURFS REQS SPECIAL PRECS. DURING EMER CNTNRS, OVEREXP TO
DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT.
GET MED ATTN. OTHER PRECS:EXPOSED AREAS. LIQ MAY PENETRATE SHOES &
LEATHER CAUSING DELAYED IRRIT. RESP PROT:GOGGS, GLOVES & SUPP NIOSH
APPROVED RESP EQUIP.

Boiling Pt:B.P. Text:>260F,>127C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:1.04
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:CLEAR LIQUID; ORGANIC ODOR.
Percent Volatiles by Volume:37.8

Stability Indicator/Materials to Avoid:YES
ALKALIS, OXIDIZERS, ALKALI METALS, WATER, AMINES, NITRIC ACID, SODIUM
HYPOCHLORITE, METAL COMPOUNDS.
Stability Condition to Avoid:OPEN FLAME, HEAT, SPARKS, MOISTURE.
Hazardous Decomposition Products:OXIDES OF CARBON & NITROGEN, VARIOUS
HYDROCARBONS, HYDROGEN CYANIDE, HEXAMETHYLENE DIISOCYANATE (HDI).

Waste Disposal Methods:DISPOSE OF I/A/W FEDERAL, STATE OR PROVINCIAL
AND LOCAL POLLUTION REQUIREMENTS. IN ADDITION, RAGS, SPRAY BOOTH
FILTERS, PAINT SUITS, EMPTY CANS, ETC, CONTAM W/PROD MAY BE HAZ
WASTE. DETERM WHETHER CON TAM ITEMS ARE HAZ & DISP OF AS APPROP.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.